25.2.49. You Must Specify Joint Conditions to all Three Rotational DOFs

...for one or more joints in the model. Refer to the Troubleshooting section in the Ansys Workbench Manual

Rotations are not independent in 3D. You must define all three rotations for a Joint Condition before proceeding to a solve. The problem is mathematically different on the velocities, as the 3 components are perfectly independent, thus you can define any of the components.