26.2.1. Modeling

When dealing with the evaluation of residual stresses and deformations, two quantities of interest are the temperature and the displacement vector. They are respectively denoted by and . In elasticity modeling, the deformation tensor is defined from the displacement vector as follows:

(26–1)

Following Chambers [6], the residual stress tensor is obtained as follows:

(26–2)

where and are the bulk and shear relaxation moduli, respectively, is the thermal strain, is the unit tensor, and is the integration variable. The residual stress tensor must also satisfy the following momentum equation at all times:

(26–3)

In a general form, the bulk and shear relaxation moduli are described by means of Prony series as follows:

(26–4)

(26–5)

where and are bulk elastic moduli, and are shear elastic moduli, and and are the relaxation times for each Prony component. In general, these moduli are characterized by and modes, respectively, and by a steady value reached after relaxation. In Equation 26–2, is a reduced time variable, which is given by the integral invoking a shift function suggested by Narayanaswamy   [26]:

(26–6)

where and are a reference temperature and the fictive temperature, respectively. In Equation 26–6, denotes the ratio of activation energy to the ideal gas constant, while is a fractional parameter ranging between 0 and 1. Often, the temperature is expressed in a non-absolute scale, and the relationship for calculating is then written as

(26–7)

where denotes the absolute zero temperature in the current scale (for example, –273 when the temperature is given in Celsius).

The fictive temperature is related to the actual temperature by means of the following equation:

(26–8)

where is a structural relaxation modulus, and is given by

(26–9)

where are the individual weights for each Prony component of the structural relaxation function and are the corresponding relaxation times.

Finally, the thermal strain in glass is a function of both temperature and fictive temperature histories. It is therefore obtained from an integral involving liquid and glassy properties described by means of the corresponding expansion coefficients and as follows:

(26–10)

where the coefficients and can be constants, or up to third-order polynomial functions of the temperature.