The effect of hydrogen cross-over from anode to cathode through the membrane is modeled by
a total leakage current (A). In addition to the source terms expressed by Equation 20–18 through Equation 20–20, the
following extra volumetric source terms are added to the corresponding equations:
(20–55) |
(20–56) |
(20–57) |
Here, and
are the volumes of the catalytic layers on the anode and cathode sides, and 2
and 4 are the numbers of electrons per mole of reactants and products.
Accordingly, the volumetric leakage current () is subtracted from the cathode transfer current (
) that is computed by Equation 20–6 and Equation 20–8.