The PTT and Giesekus models recommended for fiber spinning are also recommended for film casting. The Oldroyd-B model is another acceptable choice, especially for melts characterized by a significant strain hardening behavior. The DCPP model can also be used, especially if a qualitative description of the macromolecular behavior is required. The Leonov model, however, is not available for film casting applications. In addition, the simplified viscoelastic model is not suited for the simulation of film casting.
If no experimental data are available for the elongational viscosity, the
nonlinear parameters should be fixed on the basis of known melt properties.
Therefore, for a strain-thinning or weakly strain-hardening melt, high values for
the nonlinear parameters are selected (typically for a PTT model or
for a Giesekus model). For a strain-hardening melt, lower values
should be used for the nonlinear parameters. If the DCPP model is used, a relatively
large number of branches (
in Equation 6–49) should be considered for
strain-hardening materials such as LDPE, while a unit or low number of branches
should be selected for strain-thinning or weakly strain-hardening melts such as
LLDPE.