Irrespective of the Advection Scheme setting, the advection scheme for the turbulence model equations depends on the Turbulence Numerics option:
First Order
The Upwind advection scheme is used.
High Resolution
The High Resolution advection scheme is used.
Note that Turbulence Numerics option also specifies the transient scheme for the turbulence model equations (see Turbulence Numerics in the CFX-Pre User's Guide). This can be overridden in CFX-Pre in the Solver Control details view on the Equation Class Settings tab.