3.3.2. Input to Gas-phase Kinetics Pre-processor
ELEMENTS H N SI F
END
SPECIES
H2 H N2 N NH NH2 NNH N2H2 N2H3 N2H4
HF F SIF4 SIF3 SIHF3 SIF3NH2 NH3
END
REACTIONS
H+H+M=H2+M 0.100E+19 -1.000 0.000 ! D-L
H2/0.0/
H+H+H2=H2+H2 0.920E+17 -0.600 0.000
NH+N=N2+H 0.300E+14 0.000 0.000 ! JAM
NH+H=N+H2 0.100E+15 0.000 0.000 ! NH3 CST
NH2+H=NH+H2 0.692E+14 0.000 3650.000
NH3+H=NH2+H2 0.636E+06 2.390 10171.000 ! MICHAEL
NNH=N2+H 0.100E+05 0.000 0.000 ! JAM
NNH+H=N2+H2 0.100E+15 0.000 0.000 ! JAM
NNH+NH2=N2+NH3 0.500E+14 0.000 0.000 ! JAM
NNH+NH=N2+NH2 0.500E+14 0.000 0.000 ! JAM
NH2+NH=N2H2+H 0.500E+14 0.000 0.000 ! NH3CST
NH+NH=N2+H+H 0.254E+14 0.000 0.000 ! NH3 CST
NH2+N=N2+H+H 0.720E+14 0.000 0.000 ! PG
N2H2+M=NNH+H+M 0.500E+17 0.000 50000.000 ! NH3 CST
N2/2/ H2/2/
N2H2+H=NNH+H2 0.500E+14 0.000 1000.000 ! NH3 CST
N2H2+NH=NNH+NH2 0.100E+14 0.000 1000.000 ! NH3 CST
N2H2+NH2=NH3+NNH 0.100E+14 0.000 1000.000 ! NH3 CST
NH2+NH2=N2H2+H2 0.500E+12 0.000 0.000 ! NH3 CST
NH3+M=NH2+H+M 0.140E+17 0.000 90600.000 ! MSGK
N2H3+H=NH2+NH2 1.60E+12 0.0 0.0 ! MSGK
N2H3+M=N2H2+H+M 3.50E+16 0.0 46000.0 ! MSGK
N2H3+NH=NH2+N2H2 2.00E+13 0.0 0.0 ! MSGK
NH2+NH2+M=N2H4+M 3.00E+20 -1.0 0.0 ! MSGK
H+N2H4=H2+N2H3 1.30E+13 0.0 2500.0 ! MSGK
NH2+N2H4=NH3+N2H3 3.90E+12 0.0 1500.0 ! MSGK
NH+H+M=NH2+M 2.00E+16 -0.5 0.0 ! MSGK
NH2+NH2=NH3+NH 5.00E+12 0.0 10000.0 ! MSGK
F+NH3=NH2+HF 4.27E+11 0.5 800.0 ! KONDRATIEV
SIF4=SIF3+F 3.00E+12 0.0 147170.0 ! PHO&MEC
H+SIF4=HF+SIF3 1.00E+13 0.0 50000.0 ! PHO&MEC
NH2+SIF4=SIF3NH2+F 1.00E+11 0.0 40950.0 ! GUESS
NH3+SIF3=SIF3NH2+H 1.00E+11 0.0 5000.0 ! GUESS
NH3+SIF3=SIHF3+NH2 1.00E+11 0.0 10000.0 ! PHO&MEC
END
